Researchers have made the first battery electrode that heals itself, opening a new and potentially commercially viable path for making the next generation of lithium ion batteries for electric cars, cell phones and other devices.
The secret is a stretchy polymer that coats the electrode, binds it together and spontaneously heals tiny cracks that develop during battery operation, said the team from Stanford University and the Department of Energy’s SLAC National Accelerator Laboratory.
“Self-healing is very important for the survival and long lifetimes of animals and plants,” said Chao Wang, a postdoctoral researcher at Stanford and one of two principal authors of the paper. “We want to incorporate this feature into lithium ion batteries so they will have a long lifetime as well.”
Chao developed the self-healing polymer in the lab of Zhenan Bao, a professor of chemical engineering at Stanford, whose group has been working on flexible electronic skin for use in robots, sensors, prosthetic limbs and other applications. For the battery project, Chao added tiny nanoparticles of carbon to the polymer so it would conduct electricity.
“We found that silicon electrodes lasted 10 times longer when coated with the self-healing polymer, which repaired any cracks within just a few hours,” Bao said.
“Their capacity for storing energy is in the practical range now, but we would certainly like to push that,” said Yi Cui, an associate professor at SLAC and Stanford who led the research with Bao. The electrodes worked for about 100 charge-discharge cycles without significantly losing their energy storage capacity.
“That’s still quite a way from the goal of about 500 cycles for cell phones and 3,000 cycles for an electric vehicle,” Cui said, “but the promise is there, and from all our data it looks like it’s working.”
This prototype lithium ion battery contains a silicon electrode protected with a coating of self-healing polymer. The cables and clips in the background are part of an apparatus for testing the battery’s performance. (Photo: Brad Plummer / SLAC)
Researchers have made the first battery electrode that heals itself, opening a new and potentially commercially viable path for making the next generation of lithium ion batteries for electric cars, cell phones and other devices.
The secret is a stretchy polymer that coats the electrode, binds it together and spontaneously heals tiny cracks that develop during battery operation, said the team from Stanford University and the Department of Energy’s SLAC National Accelerator Laboratory.
Researchers worldwide are racing to find ways to store more energy in the negative electrodes of lithium ion batteries to achieve higher performance while reducing weight. One of the most promising electrode materials is silicon; it has a high capacity for soaking up lithium ions from the battery fluid during charging and then releasing them when the battery is put to work.
But this high capacity comes at a price: Silicon electrodes swell to three times their normal size and shrink back down again each time the battery charges and discharges. The brittle material soon cracks and falls apart, degrading battery performance.
To make the self-healing coating, scientists deliberately weakened some of the chemical bonds within polymers – long, chain-like molecules with many identical units. The resulting material breaks easily, but the broken ends are chemically drawn to each other and quickly link up again, mimicking the process that allows biological molecules such as DNA to assemble, rearrange and break down.
